Photorearrangements of some methyl-substituted cholest-5-en-3.BETA.-ol nitrites.

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概要

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• Photolysis of 6-methylcholest-5-en-3β-ol nitrite and 4,4,6-trimethylcholest-5-en-3β-ol nitrite in benzene with monochromatic light respectively gave a seven-membered cyclic hydroxamic acid arising from rearrangement albeit in low yields. Photolysis of 3α-methylcholest-5-en-3β-ol nitrite and 3α,4,4-trimethylcholest-5-en-3β-ol nitrite respectively gave a nitroso dimer arising from β-scission.

• 公益社団法人 日本化学会の論文

著者

• Kaji Makoto

  Organic Synthesis Division, Department of Chemical Process Engineering, Faculty of Engineering, Hokkaido University

関連論文

• Photorearrangements of some methyl-substituted cholest-5-en-3.BETA.-ol nitrites.

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