Synthesis of cyclic guanidines fused with aromatic ring through metal ion promoted cyclization.

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概要

• 論文の詳細を見る

• A convenient synthetic method of five- and six- membered cyclic guanidines fused with aromatic ring was presented. 2-Aminoaniline or 2-(aminomethyl)aniline was treated with dimethyl carbonimidodithioates to give isothiourea which was cyclized to cyclic guanidine by using soft metal cations (Ag<SUP>+</SUP>, Hg<SUP>2+</SUP>).

• 公益社団法人 日本化学会の論文

著者

• Nakamizo Nobuhiro

  Tokyo Research Laboratory, Kyowa Hakko Co., Ltd.

• Obase Hiroyuki

  Tokyo Research Laboratory, Kyowa Hakko Co., Ltd.

• Takai Haruki

  Tokyo research Laboratory, Kyowa Hakko Co., Ltd.

• Teranishi Masayuki

  Tokyo research Laboratory, Kyowa Hakko Co., Ltd.

関連論文

• Synthesis of cyclic guanidines fused with aromatic ring through metal ion promoted cyclization.

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