A kinetic study on the oxychlorination of benzene.

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概要

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• Gas-phase benzene oxychlorination was carried out over a CuCl<SUB>2</SUB>–CeCl<SUB>3</SUB>/Al<SUB>2</SUB>O<SUB>3</SUB> catalyst. A kinetic model is proposed which permits us to obtain a rate equation capable of reproducing experimental results. The presence of cerium in the catalyst increases the reaction rate and maintains the conversion level for a long time. It seems that this element facilitates copper reoxidation by making the total rate independent of the partial pressure of oxygen and stabilizes the active phase of the catalyst.

• 公益社団法人 日本化学会の論文

著者

• Blanco Jesus

  Instituto Biomar S.a. Pol. Ind. Edificio Cei

• Melo Francisco

  Instituto de Catálisis y Petroleoquimica, Serrano

• Blanco Jesus

  Instituto de Catálisis y Petroleoquimica, Serrano

• Avila Pedro

  Instituto de Catálisis y Petroleoquimica, Serrano

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• A kinetic study on the oxychlorination of benzene.

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