Polarographic study of mixed ligand (o-mercaptobenzoate-citrate) complexes of cadmium(II), lead(II), and thallium(I).

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概要

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• The mixed ligand complex formation of <I>o</I>-mercaptobenzoic acid and citric acid with Cd(II), Pb(II), and Tl(I) in aqueous KNO<SUB>3</SUB> (μ=1.0 mol dm<SUP>−3</SUP>) solutions containing Triton X-100 (0.001%) has been investigated by polarography. It was shown that only one mixed ligand entity MA<I><SUB>i</SUB></I>X<I><SUB>j</SUB></I> is formed, where <I>i</I> is two for Cd (II) and one for Tl(I) <I>j</I> is one for all complexes and A and X are the <I>o</I>-mercaptobenzoate and citrate ligands respectively. The stability constants have been evaluated.

• 公益社団法人 日本化学会の論文

著者

• Sharma Kalpana

  Post Graduate Department of Chemistry, Govt. College

関連論文

• Polarographic study of mixed ligand (o-mercaptobenzoate-citrate) complexes of cadmium(II), lead(II), and thallium(I).

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