Enthalpies of transfer of monovalent ions from water to water-acetonitrile mixtures.

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概要

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• Ionic enthalpies of transfer from water to water–acetonitrile mixtures were estimated for Na<SUP>+</SUP>, K<SUP>+</SUP>, Rb<SUP>+</SUP>, Cs<SUP>+</SUP>, Ag<SUP>+</SUP>, Tl<SUP>+</SUP>, Me<SUB>4</SUB>N<SUP>+</SUP>, Et<SUB>4</SUB>N<SUP>+</SUP>, <I>n</I>-Pr<SUB>4</SUB>N<SUP>+</SUP>, <I>n</I>-Bu<SUB>4</SUB>N<SUP>+</SUP>, Ph<SUB>4</SUB>As<SUP>+</SUP>, Ph<SUB>4</SUB>B<SUP>−</SUP>, Cl<SUP>−</SUP>, Br<SUP>−</SUP>, I<SUP>−</SUP>, NCS<SUP>−</SUP>, NO<SUB>3</SUB><SUP>−</SUP>, ClO<SUB>4</SUB><SUP>−</SUP>, and picrate ion on the basis of the assumption Δ<I>H</I><SUB>t</SUB><SUP>°</SUP>(Ph<SUB>4</SUB>As<SUP>+</SUP>)=Δ<I>H</I><SUB>t</SUB><SUP>°</SUP>(Ph<SUB>4</SUB>B<SUP>−</SUP>).

• 公益社団法人 日本化学会の論文

著者

• Morinaga Kenichi

  Department of Chemistry, Faculty of Science, Saitama University

• Miyaji Kiyoshi

  Department of Chemistry, Faculty of Science, Saitama University

関連論文

• Enthalpies of transfer of monovalent ions from water to water-acetonitrile mixtures.

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