Kinetics of oxidative coupling of phenols. Oxidation of guaiacol by alkaline hexacyanoferrate(III).

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概要

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• The reaction between guaiacol and alkaline hexacyanoferrate(III), at constant ionic strength, gave a coupled product, 3:3′-dimethoxydiphenoquinone. The rate of the reaction was dependent on the first orders of the concentrations of substrate, oxidant, and alkali. The rate determining step involved the formation of a radical intermediate, which was detected by ESR spectroscopy.

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著者

• Mahanti Mahendra

  Department Of Chemistry North-eastern Hill University

• Bhattacharjee Mitra

  Department of Chemistry, North-Eastern Hill University

• Singh Sukham

  Department of Chemistry, North-Eastern Hill University

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• Kinetics of Oxidation of Cyclic Alcohols by Quinolinium Dichromate
• Kinetics of oxidative coupling of phenols. Oxidation of guaiacol by alkaline hexacyanoferrate(III).
• Kinetics and mechanism of acid-catalyzed oxidation of substituted toluenes by pyridinium fluorochromate.
• Kinetics and mechanism of reduction of hexacyanoferrate(III) by sodium tetrahydroborate.

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