Preparation and properties of polymers anchoring biphenyl-2-ol.
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The monomer, 2-biphenylyl acrylate (BPA), was prepared and was polymerized and copolymerized with vinyl acetate (VAc), styrene and <I>N</I>-vinylpyrrolidone. The reactivity ratios of BPA (M<SUB>1</SUB>) with VAc were evaluated as <I>r</I><SUB>1</SUB>=4.6+0.4 and <I>r</I><SUB>2</SUB>=0.37+0.08. The polymers were hydrolyzed in methanol–phosphate buffer solution(pH 6 and 8), and the release rate of biphenyl-2-ol from the polymer was investigated.
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