A convenient synthesis of C(2)-substituted cephalosporins.
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概要
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Replacement of the C(2)-substituents of 2-acetoxy- or 2-methoxycephalosporin with nucleophiles was performed efficiently in dichloromethane in the presence of acid-catalysts, affording cephalosporins bearing heteroaromatic moieties, sulfenyl, and alkoxyl groups at the C(2)-position.
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関連論文
- Penicillin-cephalosporin conversion. VII. An improved synthesis of 3-methylenecephams.
- A convenient synthesis of C(2)-substituted cephalosporins.