Moessbauer effect of 119Sn in tin sulfides produced through thermal decomposition of SnS2.
スポンサーリンク
概要
- 論文の詳細を見る
The intermediate tin sulfides produced through thermal decomposition of SnS<SUB>2</SUB> were studied by quenching and Mössbauer spectroscopy. The thermal decomposition of SnS<SUB>2</SUB> in a nitrogen gas flow proceeded to SnS <I>via</I> Sn<SUB>2</SUB>S<SUB>3</SUB>. The existing phases of the decomposition products in the range of the S/Sn ratio less than 1.50 were Sn<SUB>2</SUB>S<SUB>3</SUB> and Sn<SUB>1−<I>x</I></SUB>S. A new peak observed in the Mössbauer spectrum of tin sulfides with the S/Sn ratio less than 1.04 was assigned to Sn<SUP>4+</SUP> in the nonstoichiometric compound Sn<SUB>1−<I>x</I></SUB>S.
- 公益社団法人 日本化学会の論文
著者
-
Ichiba Sumio
Department of Chemistry, Faculty of Science, Hiroshima University
-
Kunita Kazushi
Department of Chemistry, Faculty of Science, Hiroshima University
関連論文
- Structural phase transition and electrical conductivity of the perovskite CH3NH3Sn1-xPbxBr3 and CsSnBr3.
- The chemical preparation of tin organosol.
- 81Br NQR and 119Sn Moessbauer spectra for SnBr3- anions.
- Mössbauer Effect of 119Sn in Tetracarbonylcobalt Derivatives of Tin(IV) Halides
- The thermal decomposition of ammonium chloride tetrachlorozincate and the formation of tetrachlorozincate complexes of alkali metal by means of solid reactions with alkali chlorides.
- The Moessbauer effect of 119Sn in the dimethylbis(8-quinolinolato)tin(IV) single crystal.
- Moessbauer emission spectra of 119mSn in tin organosol.
- Cation distribution in a series of mixed ferrites MgxMn1.1-xSn0.1Fe1.8O4 by means of powder X-ray diffraction and 57Fe, 119Sn Moessbauer spectroscopy.
- AlBr3 group reorientation in NaAl2Br7 and KAl2Br7 studied by means of 81Br, 27Al NQR and 27Al NMR.
- 81Br NQR and 119Sn Moessbauer study for MSnBr3 (M=Cs and CH3NH3).
- Moessbauer effect in fluorotrimethyltin(IV).
- Moessbauer effect of 119Sn in tin sulfides produced through thermal decomposition of SnS2.