O- and C-perfluoroalkylations of phenol system with (perfluoroalkyl)phenyliodonium triflates.
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The reaction of FITS reagents with the phenols bearing bulky substituents at <I>C</I>-positions yielded <I>O</I>- and <I>C</I>-perfluoroalkylation products whose ratios were dependent on the steric bulkiness of the substituents or the perfluoroalkyl groups and the reaction temperature.
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関連論文
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