Heats of solution of bolaform electrolytes in water. II. Polymethylenebis(trimethylammonium) dibromides.
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概要
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The heats of solution of polymethylenebis(trimethylammonium) dibromides [(CH<SUB>3</SUB>)<SUB>3</SUB>N(CH<SUB>2</SUB>)<I><SUB>n</SUB></I>N-(CH<SUB>3</SUB>)<SUB>3</SUB>]Br<SUB>2</SUB> (<I>n</I>=3–6, 8, 10, and 12) and alkyltrimethylammonium bromides C<I><SUB>n</SUB></I>H<SUB>2<I>n</I>+1</SUB>N(CH<SUB>3</SUB>)<SUB>3</SUB>Br (<I>n</I>=2–6) in water were measured at 15, 25, and 35 °C. The hydrophobic character of the polymethylene groups was compared with that of alkyl groups on the basis of the changes in the heat capacity for dissolution, which were obtained from the relation between the heats of solution and the temperature.
- 公益社団法人 日本化学会の論文
著者
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Furuya Rie
Department Of Cell Regulation Medical Research Institute Tokyo Medical And Dental University
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Tamaki Kunio
Department of Chemistry, Yokohama City University
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Furuya Rie
Department of Chemistry, Yokohama City University
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