Polarized Raman and phosphorescence spectra of (1H4)- and (2H4)pyrimidines.
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概要
- 論文の詳細を見る
Assignments of the out-of-plane normal vibrations of [<SUP>1</SUP>H<SUB>4</SUB>]- and [<SUP>2</SUP>H<SUB>4</SUB>]pyrimidines were reexamined through studies of the polarized Raman, time-resolved phosphorescence and polarized dark sublevel phosphorescence spectra. The vibrational analyses of the phosphorescence spectra based on their polarization behavior indicate that the appearance of the strong 0-0 and totally symmetric vibronic bands in the dark sublevel phosphorescence spectra is attributed to the distortion of the molecular structure along the b<SUB>1</SUB> normal coordinates in the lowest triplet state.
- 公益社団法人 日本化学会の論文
著者
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Shimada Hiroko
Department Of Applied Chemistry Faculty Of Engineering Toyama University
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Shimada Ryoichi
Department of Chemistry, Faculty of Science, Kyushu University
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Shimada Ryoichi
Department of Chemistry, Faculty of Science, Kyushu University, 33
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Umemoto Masayuki
Yamaguchi Prefectural Environmental Pollution Research Center
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Ogata Taketora
Department of Chemistry, Faculty of Science, Fukuoka University
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