The incorporation of dicarboxylates into octacalcium bis(hydrogenphosphate) tetrakis(phosphate) pentahydrate.

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概要

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• Octacalcium bis(hydrogenphosphate) tetrakis(phosphate) pentahydrate (OCP) has been found to complex with saturated aliphatic dicarboxylate ions, C<I><SUB>n</SUB></I>H<SUB>2<I>n</I></SUB>C<SUB>2</SUB>O<SUB>4</SUB><SUP>2−</SUP>; <I>n</I>=1–6. These organic substances were incorporated, instead of HPO<SUB>4</SUB><SUP>2−</SUP>, into the "B-layer" of the OCP structure. The incorporation caused expansion in the basal spacing (<I>d</I><SUB>100</SUB>) of OCP from 18.7 Å to 19.6–26.1 Å. A possible structural model is proposed for the incorporation.

• 公益社団法人 日本化学会の論文

著者

• Monma Hideki

  National Institute for Research in Inorganic Materials

関連論文

• The incorporation of dicarboxylates into octacalcium bis(hydrogenphosphate) tetrakis(phosphate) pentahydrate.
• Succinate-complexed octacalcium phosphate.

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