Pressure and temperature effects on octahedral-tetrahedral equilibria in pyridine solutions of some cobalt(II) halides. II.
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概要
- 論文の詳細を見る
Temperature and pressure effects on the configuration equilibrium of cobalt(II) iodide in pyridine solution have been studied spectrophotometrically. High temperature favors the tetrahedral species but high pressure favors the octahedral species, the heat and volume changes being 65.3 kJ mol<SUP>−1</SUP> and −6 cm<SUP>3</SUP> mol<SUP>−1</SUP>, respectively. Comparisons among three kinds of halide are also made.
- 公益社団法人 日本化学会の論文
著者
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Kojima Kazuo
Department Of Applied Chemistry College Of Life Sciences Ritsumeikan University
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Matsuda Jiro
Department of Chemistry, Faculty of Science and Engineering, Ritsumeikan University
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Miyashita Takeru
Department of Chemistry, Faculty of Science and Engineering, Ritsumeikan University
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