Cyclosadol, isocyclosadol, and other related triterpene alcohols obtained from 24-methylenecycloartanol by acid-catalyzed isomerization.
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概要
- 論文の詳細を見る
The acid-catalyzed isomerization of 24-methylenecycloartanol with sulfuric acid afforded cyclosadol (23<I>E</I>-Δ<SUP>23</SUP>), isocyclosadol (23<I>Z</I>-Δ<SUP>23</SUP>), and other isomers, including lanostane- and cucurbitane-type isomers with (23<I>E</I>)- and (23<I>Z</I>)-Δ<SUP>23</SUP>- and Δ<SUP>24</SUP>-unsaturated side chains. The phytochemical significance of the isomers is discussed.
- 公益社団法人 日本化学会の論文
著者
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Matsumoto Taro
College Of Pharmacy Nihon University:kaken Shoyaku Co. Ltd.:national Cancer Center Research Institut
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Ichinohe Yoshiyuki
College Of Science And Technology Nihon University
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Itoh Toshihiro
College of Science and Technology, Nihon University
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Shimizu Naoto
College of Science and Technology, Nihon University
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- Cyclosadol, isocyclosadol, and other related triterpene alcohols obtained from 24-methylenecycloartanol by acid-catalyzed isomerization.