A radical-induced extrusion reaction of 2-(benzylsulfonyl)tropones to 2- and 4-benzyltropones.

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概要

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• Several 2-(benzylsulfonyl)tropones were thermolized to give 2- and 4-benzyltropones. The radical mechanism for the thermolysis was elucidated by a deuterium-labelling experiment.

• 公益社団法人 日本化学会の論文

著者

• Mametsuka Hiroaki

  Reserch Institute of Industrial Science, 86, Kyushu University

• Takeshita Hitoshi

  Reserch Institute of Industrial Science, 86, Kyushu University

• Matsuo Norihide

  Graduate School of Engineering Sciences, 39, Kyushu University

関連論文

• A radical-induced extrusion reaction of 2-(benzylsulfonyl)tropones to 2- and 4-benzyltropones.
• A dimethyl sulfoxide-mediated oxidation of arylalkyl and alkyl alcohols to corresponding aldehydes and ketones via tropolonyl ethers.

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