A study on some simple and mixed ligand N,N-disubstituted dithiocarbamates of thallium(III).

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概要

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• Neutral tris (<I>N</I>,<I>N</I>-disubstituted dithiocarbamato) thallium (III) ((TI(III)) has been prepared from acyclic dimethylamine, diethylamine, dipropylamine, dibutylamine, <I>N</I>-methylaniline, dibenzylamine, and from piperidine. Mixed ligand dithiocarbamates were found to form by ligand exchange reactions while mixing the simple, symmetric chelates in nonpolar solvents and got separated on preparative TLC layers of silica gel. These chelates were characterised by elemental analyses, IR, <SUP>1</SUP>H NMR, and electronic spectral studies.

• 公益社団法人 日本化学会の論文

著者

• Subbaiyan M.

  Department Of Analytical Chemistry University Of Madras

• Soundararajan G.

  Department of Analytical Chemistry, University of Madras, A. C. College Campus

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• A study on some simple and mixed ligand N,N-disubstituted dithiocarbamates of thallium(III).

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