A sudden-polarization model to predict excited state reactivity of .BETA.-t-butylstyrene.
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概要
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A model in which two zwitteriorts play a significant role was employed to account for solvent and substituent effects on photochemical reactions of β-<I>t</I>-butylstyrene. These zwitterions are formed by 90° rotation about the external C=C double bond. Semi-empirical MINDO/3 calculations showed that these zwitterions can be two channels which give the observed reacation products. The model also elucidated satisfactorily the photochemical reactions of para substituted β-<I>t</I>-butylstyrenes.
- 公益社団法人 日本化学会の論文
著者
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Kikuchi Osamu
Department Of Anesthesia Kitano Hospital The Tazuke Kofukai Medical Research Institute
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Yoshida Hideki
Department of Applied Biology,Kyoto Institute of Technology Graduate School
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Kikuchi Osamu
Department of Chemistry, The University of Tsukuba
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