Stereoselective oxylactonization. Preparation of 2-deoxy-DL-ribono-1,4-lactone derivatives from 3-silyloxy-4-alkenamides.
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概要
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The oxylactonization of 3-silyloxy-4-alkenamides proceeds stereoselectively by treatment with <I>m</I>-chloroperbenzoic acid to give the corresponding 2-deoxy-DL-ribono-1,4-lactone derivatives.
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- Stereoselective oxylactonization. Preparation of 2-deoxy-DL-ribono-1,4-lactone derivatives from 3-silyloxy-4-alkenamides.