The electrochemical behavior of BR2-linked bis(glyoximato)nickel(II) complexes in a nonaqueous solvent.

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概要

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• Nickel(II) complexes with dioximers replaced by BF<SUB>2</SUB> and B(C<SUB>2</SUB>H<SUB>5</SUB>)<SUB>2</SUB> groups for bridging by the hydrogen atom were investigated by electrochemical methods. The nickel(II) complexes exhibited two distinct one-electron reduction waves in <I>N</I>,<I>N</I>-dimethylformamide. It was found that the electron-withdrawing effect of the replaced group is exerted on the electronic states of the nickel(II) complexes.

• 公益社団法人 日本化学会の論文

著者

• Aihara Makoto

  Laboratory of Inorganic Chemistry, Faculty of Home Life Science, Fukuoka Women's University

• Nishi Yumiko

  Laboratory of Inorganic Chemistry, Faculty of Home Life Science, Fukuoka Women's University

• Omatsu Hiroko

  Laboratory of Inorganic Chemistry, Faculty of Home Life Science, Fukuoka Women's University

• Nonaka Yasuomi

  Fukuoka Jogakuin Junior College

• Omatsu Hiroko

  Laboratory of Inorganic Chemistry, Faculty of Home Life Science, Fukuoka Women's University

関連論文

• The electrochemical behavior of BR2-linked bis(glyoximato)nickel(II) complexes in a nonaqueous solvent.
• Response of copper(II) and cadmium(II) ion-selective electrodes in some nonaqueous solvents.
• Potentiometric study of copper(II) complexes with .BETA.-diketone in micellar solution using a copper(II) ion-selective electrode.

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