A CIDEP study of the addition of trialkylsilyl radicals to substituted p-benzoquinones.
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概要
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Evidence has been obtained through the combined ESR and CIDEP techniques for the two distinct pathways in which trialkylsilyl radicals add to substituted <I>p</I>-benzoquinones <I>via</I> the carbonyl oxygen as well as the ring carbon–carbon double bonds. The results represent the first observation of CIDEP from organic radicals containing an organosilyl group in solution.
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