Substituent effects on cation-extraction and transport properties of a series of 4'-substituted benzo-15-crown-5 derivatives.
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概要
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The substituent effects on chemical functions of benzo-15-crown-5 derivatives were found to be considerably large and often comparable to the ring-size effects. For example, 4′-aminobenzo-15-crown-5 transported K<SUP>+</SUP> ion 14-times faster than 4′-nitrobenzo-15-crown-5, while 4′-nitrobenzo-18-crown-6 showed 12-times higher transport rate than 4′-nitrobenzo-15-crown-5.
- 公益社団法人 日本化学会の論文
著者
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Tsukube Hiroshi
Department Of Chemistry College Of Liberal Arts & Science Okayama University
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Iwachido Tadashi
Department Of Chemistry Faculty Of Science Okayama University
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Hayama Naomi
Department Of Chemistry College Of General Education Okayama University
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Takagi Kentaro
Department Of Applied Physics And Chemistry The University Of Electro-communications
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Higashiyama Tatsuo
Department of Chemistry, College of Liberal Arts and Science, Okayama University
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Higashiyama Tatsuo
Department of Chemistry, College of Liberal Arts & Science, Okayama University
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