Extractability of copper(II) and zinc(II) with crown ethers as picrates.
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概要
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The extraction of copper(II) and zinc(II) with picrate ion and 12-crown-4(1,4,7,10-tetraoxacyclododecane) or 15-crown-5(1,4,7,10,13-pentaoxacyclopentadecane) into benzene or chloroform has been measured. The extraction of copper(II) is better than that of zinc(II), in spite of the similar ionic size, although the difference is much smaller than that in the extraction of these metal ions with β-diketones.
- 公益社団法人 日本化学会の論文