Solvent effect on adsorption of TCNQ onto metal oxides.

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概要

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• 7,7,8,8-Tetracyanoquinodimethan(TCNQ) was adsorbed on the surfaces of alumina and titania from three basic solvents. The amount of TCNQ adsorbed decreased with an increase in the acid-base interaction between TCNQ and the basic solvent for both metal oxides. The TCNQ anion radicals were formed as a result of electron transfer from the metal oxide surfaces to adsorbed TCNQ. Further, the concentration of TCNQ anion radicals formed on the oxides after the TCNQ adsorption decreased also with an increase in the acid-base interaction between TCNQ and the basic solvent.

• 公益社団法人 日本化学会の論文

著者

• Miyata Kazuaki

  Department of Applied Chemistry, Institute of Colloid and Interface Science, Science University of Tokyo

関連論文

• Solvent effect on adsorption of TCNQ onto metal oxides.

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