The magnetic field effects on the electrolysis of hexacyanoferrate(II) oxidation and hexacyanoferrate(III) reduction.
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概要
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The effects of a magnetic field on electrolytic currents in hexacyanoferrate(II) and hexacyanoferrate(III) solutions were studied under various conditions by means of potentiometry. These effects were observed for a wide range of current densities (10<SUP>−6</SUP>–10<SUP>−3</SUP> A/cm<SUP>2</SUP>). The results were interpreted in terms of the magnetohydrodynamic effect, including a change in the solution density during electrolysis. The present observation suggests that a magnetohydrodynamic flow strongly affects the electrochemical processes on an electrode surface.
- 公益社団法人 日本化学会の論文
著者
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TANIMOTO Yoshifumi
Institute for Molecular Science
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NAKAGAKI Ryoichi
Institute for Molecular Science
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NAGAKURA Saburo
Institute for Molecular Science
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WATANABE Takeshi
Institute for Molecular Science
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Hiramatsu Mitsuo
Institute for Molecular Science
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Sakata Tadayoshi
Institute for Molecular Science
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