Iodination of benzene with iodine and metal salts in acidic solvents.
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概要
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Iodobenzene was obtained by a reaction of benzene with molecular iodine in trifluoromethanesulfonic acid in oxygen atmosphere in the presence of vanadium salt as a catalyst. The method affords a new aromatic iodination process in which benzene is iodinated directly with molecular iodine.
- 公益社団法人 日本化学会の論文
著者
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Shimizu Atsushi
Technical Development Department of Petrochemical Intermediates, Asahi Chemical Ind. Co., Ltd.
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Yamataka Kazunori
Technical Development Department of Petrochemical Intermediates, Asahi Chemical Ind. Co., Ltd.
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Isoya Toshiro
Technical Development Department of Petrochemical Intermediates, Asahi Chemical Ind. Co., Ltd.