The co-amination of phenol and cyclohexanol with palladium-on-carbon catalyst in the liquid phase. An application of a hydrogen-transfer reaction.
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概要
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Phenol and Cyclohexanol are simultaneously aminated to aniline and cyclohexylamine by ammonolysis with the palladium-on-carbon catalyst in the liquid phase, although the amination of either phenol or cyclohexanol hardly occurs without the other. In contrast, carbon-supported ruthenium, rhodium, and platinum catalysts are ineffective for this co-amination; they are active only for the amination of cyclohexanol to cyclohexylamine. These results are explained by the specific activity of palladium for hydrogen transfer between phenol and cyclohexanol.
- 公益社団法人 日本化学会の論文
著者
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Hamada Hideaki
National Chemical Laboratory For Industry
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Matsuzaki Takehiko
National Institute Of Advanced Industrial Science And Technology (aist)
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YAMAMOTO Makoto
Tokyo University of Science
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Wakabayashi Katsuhiko
National Chemical Laboratory for Industry
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Kuwahara Yasushi
National Chemical Laboratory for Industry
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