Synthesis of ketazines from dinitrogen coordinated to tungsten.

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概要

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• When treated with a methanol/acetone mixture at 50 °C, the complex <I>trans</I>-[W(N<SUB>2</SUB>)<SUB>2</SUB>(PPh<SUB>2</SUB>Me)<SUB>4</SUB>] gives acetone azine in moderate yield, although the yield is slightly lower than that from <I>cis</I>-[W(N<SUB>2</SUB>)<SUB>2</SUB>(PMe<SUB>2</SUB>Ph)<SUB>4</SUB>]. Under UV irradiation, these dinitrogen complexes produce acetone azine even at room temperature.

• 公益社団法人 日本化学会の論文

著者

• Hidai Masanobu

  Engineering Research Institute, Faculty of Engineering, The University of Tokyo

• Mizobe Yasushi

  Engineering Research Institute, Faculty of Engineering, The University of Tokyo

• Kurano Masa-aki

  Engineering Research Institute, Faculty of Engineering, The University of Tokyo

関連論文

• Synthesis of ketazines from dinitrogen coordinated to tungsten.
• Electrochemical reduction of carbon dioxide using iron-sulfur clusters as catalyst precursors.

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