X-ray photoelectron spectra of halogen-bridged one-dimensional PdII-PdIV mixed-valence complexes, (Pd(en)2)(PdX2(en)2)(ClO4)4.

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概要

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• X-Ray photoelectron spectra of [Pd<SUP>II</SUP>(en)<SUB>2</SUB>][Pd<SUP>IV</SUP>X<SUB>2</SUB>(en)<SUB>2</SUB>](ClO<SUB>4</SUB>)<SUB>4</SUB> (en=ethylenediamine, X=Cl and Br) were measured. The difference in the binding energies of Pd3d between Pd<SUP>II</SUP> and Pd<SUP>IV</SUP> in the bromo-bridged complex is smaller than that in the chloro-bridged complex. This result is consistent with those of the crystal structures, electrical conductivities, and electronic spectra previously reported.

• 公益社団法人 日本化学会の論文

著者

• IKEMOTO Isao

  Department of Chemistry, Faculty of Science, Tokyo Metropolitan University

関連論文

• X-ray photoelectron spectra of halogen-bridged one-dimensional PdII-PdIV mixed-valence complexes, (Pd(en)2)(PdX2(en)2)(ClO4)4.

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