Photolytic formation of a uranium(V)-DMSO complex and the paramagnetic shift of DMSO by uranium(V).
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概要
- 論文の詳細を見る
A U(V)-DMSO complex (DMSO=dimethyl sulfoxide) formed by photoreduction of [UO<SUB>2</SUB>(dmso)<SUB>5</SUB>]<SUP>2+</SUP> was stable in acid-free DMSO and a small quantum yield of U(V) was attributed to the difficulty in electron transfer from ligands to U(VI). The paramagnetic shift of DMSO by U(V) indicates that only the pseudo-contact shift is induced.
- 公益社団法人 日本化学会の論文
著者
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Harazono Toshie
Research Center Mitsubishi Chemical Co. Ltd.
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Fukutomi Hiroshi
Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology
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