Vibrational spectrum of 2-aminopyrazine.
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概要
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Infrared and polarized laser Raman spectra in the solid phase and in the solution phase in different solvents have been obtained within the spectral region between 4000 and 200 cm<SUP>−1</SUP> and analyzed for the purpose of vibrational assignments. The impact of intermolecular hydrogen bonding on amino group frequencies has been discussed in length. The fundamentals arising out of aromatic nucleus in particular various assignments are consistent with predicted spectral changes due to the presence of strong electron-activating amino group resulting in considerable perturbation of the vibrational levels of "parent" molecule pyrazine.
- 公益社団法人 日本化学会の論文
著者
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Kalkar Arun
Department of Chemical Technology, University of Bombay
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Ars Comakshi
Department of Chemical Technology, University of Bombay