Electrochemical properties of adriamycin adsorbed on pyrolytic graphite electrodes modified by phospholipid monomolecular membranes.
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概要
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Electrochemical equilibrium and kinetic parameters have been determined by means of numerical simulation of d.c. voltammograms based on the theory of a two-step surface-redox reaction for the case of the redox system of adriamycin adsorbed on a basal-plane pyrolytic graphite electrode (BPGE) which is modified by a phospholipid monomolecular membrane. Comparison of these parameters with those obtained at a bare BPGE has shown that thesemiquinone formation reaction is thermodynamically favorable and that the electron transfer rate constant decreases in these lipid membranes.
- 公益社団法人 日本化学会の論文
著者
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KANO Kenji
Gifu Pharmaceutical University
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KONSE Tomonori
Gifu Pharmaceutical University
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Kubota Tanekazu
Gifu College of Pharmacy
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Kano Rika
Gifu Pharmaceutical University
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