Synthesis of selenoxides by oxidation of selenides with t-butyl hypochlorite, and its application for synthesis of optically active selenoxide.

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概要

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• An effective synthesis of selenoxides by the oxidation of selenides with <I>t</I>-butyl hypochlorite in the presence of methanol and pyridine followed by hydrolysis is descrived. This oxidation method is particularly effective for the oxidation of selenides which possess electron-withdrawing groups. A synthesis of partially optically active selenoxide with bulky substituents can be achieved using a novel oxidation method.

• 公益社団法人 日本化学会の論文

著者

• Ohkubo Hiromi

  Department of Chemistry, Faculty of Science, Tokyo Metropolitan University

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• Synthesis of selenoxides by oxidation of selenides with t-butyl hypochlorite, and its application for synthesis of optically active selenoxide.

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