Stereoselective preparation of acyclic syn-.BETA.-amino alcohols from .BETA.-hydroxy ketones via the corresponding O-benzyl oximes.

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概要

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• Reduction of β-hydroxy ketone <I>O</I>-benzyl oximes with lithium aluminum hydride in the presence of sodium or potassium methoxide afforded the corresponding <I>syn</I>-β-amino alcohols in highly stereoselective manner. A lythraceae alkaloid, lasubine II, was synthesized stereoselectively by applying this method.

• 公益社団法人 日本化学会の論文

著者

• Yamazaki Shigeru

  Department of Chemistry, Faculty of Science, The University of Tokyo

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• Stereoselective preparation of acyclic syn-.BETA.-amino alcohols from .BETA.-hydroxy ketones via the corresponding O-benzyl oximes.

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