The effect of intermolecular association on kinetic behavior. Rate acceleration with time in oxidation of a pair of thiols.

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概要

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• In base-catalyzed oxidation of a pair of associating thiols [HSCH<SUB>2</SUB>–CONHCONH–Ph and HSCH<SUB>2</SUB>CH<SUB>2</SUB>–NHCONHCO–C<SUB>6</SUB>H<SUB>13</SUB>], rate enhancement with time occurred in protic media, whereas the rate was reduced with time in aprotic solvents. For a pair of nonassociating thiols [HSCH<SUB>2</SUB>CO<SUB>2</SUB>C<SUB>2</SUB>H<SUB>5</SUB> and HSCH<SUB>2</SUB>CH<SUB>2</SUB>OH], the rate enhancement was neither observed in a protic solvent nor in an aprotic one.

• 公益社団法人 日本化学会の論文

著者

• Hagino Kazuomi

  College of Science and Engineering, Aoyama Gakuin University

• Ito Masato

  College of Science and Engineering, Aoyama Gakuin University

• Ogikubo Toshikazu

  College of Science and Engineering, Aoyama Gakuin University

• Ueda Hideki

  College of Science and Engineering, Aoyama Gakuin University

• Endo Tadashi

  College of Science and Engineering, Aoyama Gakuin University

関連論文

• The effect of intermolecular association on kinetic behavior. Rate acceleration with time in oxidation of a pair of thiols.

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