Stereoselective reduction of symmetrical diketones with biological methods. Microbial reduction of cis-2,7-decalindione.
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概要
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The <I>pro</I>-<I>S</I> group of two enantiotopic carbonyl groups in <I>cis</I>-2,7-decalindione was preferentially reduced with <I>Rhodotorula rubra</I> to give (−)-(7<I>S</I>,9<I>R</I>,10<I>S</I>)-7-hydroxy-<I>cis</I>-2-decalone of high optical purity.
- 公益社団法人 日本化学会の論文