Mechanism of photochemical reaction from benzyl chloride to toluene in solution.
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概要
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The photochemical reaction from benzyl chloride to toluene has been investigated in rigid glasses and fluid solutions. The experimental results indicate that toluene formation from benzyl chloride in 2-methylpentane proceeds via hot benzyl radicals or higher triplet states that are isoenegitic to the vibrationless level of the S<SUB>1</SUB> state of BzCl and proceeds negligibly from stable benzyl radicals.
- 公益社団法人 日本化学会の論文
著者
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TAKEMURA Takeshi
Research Institute of Applied Electricity, Hokkaido University
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Takemura Takeshi
Research Institute For Electronic Science Hokkaido University
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Fujita Masahisa
Research Institute of Applied Electricity, Hokkaido University
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- Mechanism of photochemical reaction from benzyl chloride to toluene in solution.