Thermal and photochemical electron-transfer reactions of 4-chlorobiphenyl with lithium diisopropylamides and diisopropylamine.
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概要
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A reaction of 4-chlorobiphenyl with lithium diisopropylamide in a polar solvent gave 3- and 4-(diisopropylamino)biphenyl together with biphenyl, similar to the case of photoinduced reactions of 4-chlorobiphenyl with diisopropylamine. A common electron-transfer mechanism is proposed.
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