Synthesis of sulfoxide-modified cellulose derivatives designed for the permselective membrane of sulfur dioxide.

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概要

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• The Michael type addition reaction of cellulose with a series of vinyl sulfoxides, namely methyl vinyl sulfoxide, ethyl vinyl sulfoxide, <I>t</I>-butyl vinyl sulfoxide, and phenyl vinyl sulfoxide, was performed with NaOH as a catalyst to produce 2-(alkyl- or arylsulfinyl)ethyl cellulose derivatives. The high permselectivity of sulfur dioxide against nitrogen and oxygen was achieved through these sulfoxide modified cellulose membranes.

• 公益社団法人 日本化学会の論文

著者

• Shiomi Tomoo

  Department Of Materials Science And Technology Nagaoka University Of Technology

• Tezuka Yasuyuki

  Department Of Chemistry And Materials Technology Kyoto Institute Of Technology

• Imai Kiyokazu

  Department of Electrical and Electronic Engineering, Kisarazu National College of Technology, 2-11-1 Kiyomidai-higashi, Kisarazu, Chiba 292-0041, Japan

• Imai Kiyokazu

  Department of Material Science and Technology, Technological University of Nagaoka

• Takada Matsunori

  Department of Material Science and Technology, Technological University of Nagaoka

• Shiomi Tomoo

  Department of Material Science and Technology, Technological University of Nagaoka

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