Mixed ligand complexes of trivalent metal ions with an amine-N-polycarboxylate and fluoride.
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概要
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The formation constants of the mixed ligand complexes MLF(M : Al<SUP>3+</SUP>, Ga<SUP>3+</SUP>, In<SUP>3+</SUP>, Fe<SUP>3+</SUP>, Sc<SUP>3+</SUP>, Y<SUP>3+</SUP>, La<SUP>3+</SUP>; L: nta<SUP>3−</SUP>, hedta<SUP>3−</SUP>, edta<SUP>4−</SUP>, cdta<SUP>4−</SUP>) were determined. Reactivity of a trivalent metal ion with fluoride generally decreases by the coordination of an amine-<I>N</I>-polycarboxylate. From the decrease the structures of the parent and mixed ligand complexes are discussed.
- 公益社団法人 日本化学会の論文
著者
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Yuchi Akio
Department Of Applied Chemistry Graduate School Of Engineering Nagoya Institute Of Technology
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Wada Hiroko
Department Of Applied Chemistry Nagoya Insitute Of Technology
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Hotta Hitoshi
Department of Applied Chemistry, Nagoya Institute of Technology
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Nakagawa Genkichi
Department of Applied Chemistry, Nagoya Institute of Technology
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