Lanthanoid chirality as a tool for assignment of f-f transitions. Tb3+ and Tm3+ diglycolate.

スポンサーリンク

概要

• 論文の詳細を見る

• Although chiral studies have proved to be handy in the assignment of transitions in biological molecules, organic molecules and transition metal complexes, its potentiality for lanthanoid transition needs to be demonstrated. The paper explores the usefulness of CD studies in the assignment of lanthanoid transitions with two specific chiral single crystals–thulium diglycolate (Tm<SUP>3+</SUP>–DG) and terbium diglycolate (Tb<SUP>3+</SUP>–DG). It has been shown that chirality can distinguish Δ<I>J</I>=0, ±1 transition from others. The need for studies under higher resolution has been pointed out.

• 公益社団法人 日本化学会の論文

著者

• Karmakar Bhutnath

  Department of Physical Chemistry, Indian Association for the Cultivation of Science

• Chatterjee Prabir

  Department of Physical Chemistry, Indian Association for the Cultivation of Science

• Basu Samita

  Department of Physical Chemistry, Indian Association for the Cultivation of Science

• Chowdhury Mihir

  Department of Physical Chemistry, Indian Association for the Cultivation of Science

関連論文

• Lanthanoid chirality as a tool for assignment of f-f transitions. Tb3+ and Tm3+ diglycolate.

スポンサーリンク