Hydrogenation of aromatic nitro compounds with a Pt/SiO2-AlPO4 catalyst.

スポンサーリンク

概要

• 論文の詳細を見る

• In this work we have carried out the reduction of aromatic nitro compounds bearing different substituents with gaseous hydrogen, over a Pt catalyst (3% by weight) supported on a SiO<SUB>2</SUB>–AlPO<SUB>4</SUB> system. The catalyst was obtained by impregnation, the impregnating metal salt being reduced with α-phellandrene. The kinetic data found allow us to describe the reduction of nitrobenzene as a Langmuir–Hinslwood kinetic. The sequence of reaction rates for the different nitro compounds assayed conforms to the Hammett–Taft equation, which allows relating the electron density of the aromatic ring to the reduction rate of the nitro group. Finally, we propose mechanism for the process, characterized by the absence of intermediates with net charges.

• 公益社団法人 日本化学会の論文

著者

• Rodero Luque

  Department of Organic Chemistry, Faculty of Sciences, Córdoba University

• Marinas Rubio

  Department of Organic Chemistry, Faculty of Sciences, Córdoba University

• Jiménez Sanch\ridr\rian

  Department of Organic Chemistry, Faculty of Sciences, Córdoba University

• Aramendía Lopidana

  Department of Organic Chemistry, Faculty of Sciences, Córdoba University

• Borau Bolos

  Department of Organic Chemistry, Faculty of Sciences, Córdoba University

関連論文

• Hydrogenation of aromatic nitro compounds with a Pt/SiO2-AlPO4 catalyst.

スポンサーリンク