Synthesis and structure of the diterpenoid peucelinendiol.

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概要

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• The synthesis of peucelinendiol has been carried out starting from geraniol, and using as a key intermediates the anion of phenylthiogeraniol and (−)-geraniol epoxide obtained by the Sharpless procedure. Its structure was stablished as (6<I>S</I>,7<I>R</I>)-7-hydroxymethyl-2,6,10,14-tetramethylpentadeca-2,9,13-trien-6-ol. Isopeucelinendiol, epipeucelinendiol, and epiisopeucelinendiol were also synthesized.

• 公益社団法人 日本化学会の論文

著者

• Moran Joaquin

  Department Of Organic Chemistry University Of Salamanca

• Moran Joaquín

  Department of Organic Chemistry, F. C. Químicas, University of Salamanca

• Alcazar Victoria

  Department of Organic Chemistry, F. C. Químicas, University of Salamanca

• Grande Manuel

  Department of Organic Chemistry, F. C. Químicas, University of Salamanca

関連論文

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• Synthesis and structure of the diterpenoid peucelinendiol.

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