35Cl NQR study and addition reactions to cyclohexene of cyclic N-chloro amides (imides).

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概要

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• <SUP>35</SUP>Cl NQR frequencies were measured for <I>N</I>-chloro-2-pyrrolidinone, <I>N</I>-chloro-4,4-dimethyl-2-oxazolidinone, <I>N</I>-chloro-2-oxazolidinone, <I>N</I>-chloroglutarimide, and <I>N</I>-chlorosuccinimide. The ionicities of the N–Cl bonds were estimated on the basis of those measurements. These ionicities were related to the total yields of the 1,2-addition in the photochemical reaction with cyclohexene. When the value of the ionicity neared zero, the total yield increased.

• 公益社団法人 日本化学会の論文

著者

• Katagiri Shigeyoshi

  Department Of Chemistry Faculty Of Science Hirosaki University

• Nagao Yoshitaka

  Department Of Chemistry Faculty Of Science Hirosaki University

関連論文

• Experimental and Computational Studies on the Dipole Moments of Annulated-Tropones and 1,4-Polyacenequinones
• Thermal Study and 35Cl NQR Spectra on Alkali MetalSalts of Chloranilic, Acid
• ^Cl NQR due to the N-Cl Bonds and 1,2-Addition Reaction to Cyclohexene of N-Chloro Amide Compounds
• ^C1 NQR Spectra of 1,3-Dichloro-5,5-diphenylhydantoin and Related Compounds
• Bond Orbital Calculations on the Methane and Silane Molecules
• Bond orbital calculations on the methane and silane molecules. II. Vertical transition energies of the lower singlet-excited states of CH4.
• 35Cl NQR study and addition reactions to cyclohexene of cyclic N-chloro amides (imides).
• 35Cl NQR and ionicities of a few N-chloroimides.

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