New series of organic metal. Radical salts of Unsymmetrical donors containing pyrazino group.
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概要
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The I<SUB>3</SUB>, ClO<SUB>4</SUB>, and PF<SUB>6</SUB> salts of unsymmetrical donors containing fused pyrazino groups (DMPDSDTF and DM(DMP)DSDTF) were prepared electrochemically and their electrical conductivities were measured. The I<SUB>3</SUB> salt of DM(DMP)DSDTF exhibited a metallic behavior down to about 120 K. The radical salts of unsymmetrical donors showed much larger conductivities than those of the corresponding symmetrical donors containing pyrazino groups.
- 公益社団法人 日本化学会の論文