Diverse kinetic behaviors of the .BETA.-structure formation. A study on poly(S-carboxymethyl-L-cysteine).

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概要

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• The pH jump kinetics of random coil-to-β-structure convertsion of poly(<I>S</I>-carboxymethyl-L-cysteine) were examined on two samples of degree of polymerization (DP) of 330 and 560. Various kinetic behaviors were observed depending on polymer chain length and concentration: single exponential with or without a lag and two exponential behavior. In unbuffered solutions, the rate enhancement of β-formation was confirmed.

• 公益社団法人 日本化学会の論文

著者

• Hattori Hideyuki

  Department of Chemistry, Faculty of Science, Nagoya University

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• Diverse kinetic behaviors of the .BETA.-structure formation. A study on poly(S-carboxymethyl-L-cysteine).

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