Photochemical generation of .MU.-amido-.MU.-peroxo-bis[bis(ethylenediamine)cobalt(III)] complex from the corresponding .MU.-hyperoxo complex in neutral aqueous solution.

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概要

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• A μ-amido-μ-hyperoxo complex, [(en)<SUB>2</SUB>Co(NH<SUB>2</SUB>,O<SUB>2</SUB><SUP>−</SUP>)Co(en)<SUB>2</SUB>]<SUP>4+</SUP>, was found to generate the corresponding μ-peroxo complex, together with mononuclear cobalt(III) complexes upon irradiation with near-ultraviolet light in a neutral aqueous solution. The result is different from that obtained in an acidic aqueous solution, in which the products are [Co(NH<SUB>3</SUB>)(en)<SUB>2</SUB>(H<SUB>2</SUB>O)]<SUP>3+</SUP> and Co<SUB>aq</SUB><SUP>2+</SUP>. The photochemical reaction mechanisms are discussed.

• 公益社団法人 日本化学会の論文

著者

• Shinohara Nobuyoshi

  Department Of Chemistry Yokohama City University

• Kose Emiko

  Department of Chemistry, Yokohama City University

• Ohkubo Wataru

  Department of Chemistry, Yokohama City University

関連論文

• Production of Sb(IV) Chloro Complex by Flash Photolysis of the Corresponding Sb(III) and Sb(V) Complexes in CH_3CN and CHCl_3
• Photochemistry of μ-Amido-μ-hyperoxo-dicobalt(III) Complexes with Ammine and Polyamine Ligands in Aqueous Solutions: Effects of Ligand and pH
• Enrichment of Phosphorus-32 by Activation of Tripolyphosphate
• Photochemical generation of .MU.-amido-.MU.-peroxo-bis[bis(ethylenediamine)cobalt(III)] complex from the corresponding .MU.-hyperoxo complex in neutral aqueous solution.

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