[Cycloalkyl(phenylseleno)methylene]triphenylphosphoranes: synthesis and reactions of (phenylseleno)alkenes.
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概要
- 論文の詳細を見る
The Wittig reaction of [cyclopropyl(phenylseleno)methylene]- and [cyclobutyl(phenylseleno)methylene]triphenylphosphoranes with aldehydes produced (<I>Z</I>)- and (<I>E</I>)-(1-cyclopropyl-1-phenylseleno)- and (1-cyclobutyl-1-phenylseleno)alkenes in moderate to good yields. The oxidation of the (<I>E</I>)-selenoalkenes to the corresponding selenoxides and subsequent thermolysis of the selenoxides led to cyclopropyl- and cyclobutylacetylene derivatives in good yields.
- 公益社団法人 日本化学会の論文
著者
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Okada Yoshiharu
Department Of Applied Chemistry Kyushu Institute Of Technology
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Minami Toru
Department Of Applied Chemistry Kyushu Institute Of Technology
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Umezu Yasuo
Department of Chemistry, Kyushu Institute of Technology
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Shikita Shoji
Department of Applied Chemistry, Kyushu Institute of Technology
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Umezu Yasuo
Department of Applied Chemistry, Kyushu Institute of Technology
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