Viscosity b-coefficients of tetraalkylammonium bromides in 2-methoxyethanol at 25.DEG.C.
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概要
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The relative viscosities of solutions of tetraalkylammonium bromides, R<SUB>4</SUB>NBr, (R=C<SUB>2</SUB>H<SUB>5</SUB> to C<SUB>7</SUB>H<SUB>15</SUB>) have been measured in 2-methoxyethanol (ME) at 25 °C. The data have been analyzed in the form of associated electrolytes and the <I>B</I>-coefficients have been evaluated. The ionic <I>B</I>-values have been determined using the "reference electrolytes" viz. Bu<SUB>4</SUB>NBBu<SUB>4</SUB> and Bu<SUB>4</SUB>NBPh<SUB>4</SUB>. The results have been discussed on the basis of Einstein's equation and in terms of a transition state treatment.
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著者
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Dasgupta Debasis
Department of Chemistry, North Bengal University
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Das Susanta
Department of Chemistry, North Bengal University
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Hazra Dilip
Department of Chemistry, North Bengal University