Preparation of perfluoroalkyl ketones by the reaction of perfluoroalkyllithiums with esters.

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概要

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• A variety of esters react with perfluoroalkyllithiums in situ generated from perfluoroalkyl iodides and methyllithium to give perfluoroalkyl ketones in good yields. Perfluoroalkyllithiums add to α, β-unsaturated esters only in the 1,2-addition mode even in the presence of copper salt. Exception was observed in the reaction with maleates where perfluoroalkylated succinic esters and normal 1,2-addition products are obtained in comparable amounts.

• 公益社団法人 日本化学会の論文

著者

• Uno Hidemitsu

  Advanced Instrumentation Center for Chemical Analysis, Department of Chemistry, Faculty of Science, Ehime University

関連論文

• Preparation of perfluoroalkyl ketones by the reaction of perfluoroalkyllithiums with esters.

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